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  1. ABSTRACT

    Methylamine has been the only simple alkylamine detected in the interstellar medium for a long time. With the recent secure and tentative detections of vinylamine and ethylamine, respectively, dimethylamine has become a promising target for searches in space. Its rotational spectrum, however, has been known only up to 45 GHz until now. Here we investigate the rotation-tunnelling spectrum of dimethylamine in selected regions between 76 and 1091 GHz using three different spectrometers in order to facilitate its detection in space. The quantum number range is extended to J = 61 and Ka = 21, yielding an extensive set of accurate spectroscopic parameters. To search for dimethylamine, we refer to the spectral line survey ReMoCA carried out with the Atacama Large Millimeter/submillimeter Array towards the high-mass star-forming region Sagittarius B2(N) and a spectral line survey of the molecular cloud G+0.693–0.027 employing the IRAM 30 m and Yebes 40 m radio telescopes. We report non-detections of dimethylamine towards the hot molecular cores Sgr B2(N1S) and Sgr B2(N2b) as well as G+0.693−0.027 which imply that dimethylamine is at least 14, 4.5, and 39 times less abundant than methylamine towards these sources, respectively. The observational results are compared to computational results from a gas-grain astrochemical model. The modelled methylamine to dimethylamine ratios are compatible with the observational lower limits. However, the model produces too much ethylamine compared with methylamine which could mean that the already fairly low levels of dimethylamine in the models may also be too high.

     
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  2. Binary interactions dominate the evolution of massive stars, but their role is less clear for low- and intermediate-mass stars. The evolution of a spherical wind from an asymptotic giant branch (AGB) star into a nonspherical planetary nebula (PN) could be due to binary interactions. We observed a sample of AGB stars with the Atacama Large Millimeter/submillimeter Array (ALMA) and found that their winds exhibit distinct nonspherical geometries with morphological similarities to planetary nebulae (PNe). We infer that the same physics shapes both AGB winds and PNe; additionally, the morphology and AGB mass-loss rate are correlated. These characteristics can be explained by binary interaction. We propose an evolutionary scenario for AGB morphologies that is consistent with observed phenomena in AGB stars and PNe.

     
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